2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine , 185346-09-2

Synonym(s):
(3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;(3aS,8aR)-in-pybox

CAS NO.：185346-09-2

Empirical Formula: C25H19N3O2

Molecular Weight: 393.44

MDL number: MFCD05861599

PRODUCT Properties

• Melting point: 265°C (dec.)
• Boiling point: 633.0±55.0 °C(Predicted)
• alpha: -364.0° (c 1.04, CH2Cl2)
• Density: 1.50±0.1 g/cm3(Predicted)
• storage temp.: Sealed in dry,Room Temperature
• pka: 4.35±0.20(Predicted)
• form: Powder
• color: white to off-white
• optical activity: [α]20/D -375°, c = 1 in dichloromethane (typical)
• InChIKey: BZSJUFJXCHHRHW-LUKWVAJMSA-N
• SMILES: C1(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=NC(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=CC=C1

Description and Uses

Reactant involved in synthesis of:

• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
• Chiral N,N,N-tridentate pybos and pyboxazine ligands

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302
• Precautionary statements: P280-P305+P351+P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36/37/39-36
• WGK Germany: 3
• HS Code: 29333990