Dibromoborane methyl sulfide complex , 1.0Msolutioninmethylenechloride , 55671-55-1

Synonym(s):
Dibromoborane dimethyl sulfide;Dibromoborane dimethyl sulfide solution;Boron dibromide methyl sulfide complex;Dibromo(dimethyl sulfide)(hydro)boron;Dibromo(dimethyl sulfide)(hydro)boron solution

CAS NO.：55671-55-1

Empirical Formula: C2H10BBr2S

Molecular Weight: 236.78

MDL number: MFCD28505603

PRODUCT Properties

• Melting point: 30-35 °C(lit.)
• Density: 1.415 g/mL at 25 °C
• Flash point: 80 °F
• form: solid
• BRN: 4449985
• InChI: InChI=1S/C2H8BBr2S/c1-6(2)3(4)5/h3,6H,1-2H3
• InChIKey: PGSRDLGPKTVELT-UHFFFAOYSA-N
• SMILES: [B+3]([H-])([Br-])([Br-])S(C)C

Description and Uses

Reactant for:

• Reductive elimination C-C bond forming reactions
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates
• Preparation of boron analogues of uracil
• Boronation reactions for formation of cyclic boronium salts
• Hydroboration reactions
• Ring opening of terminal epoxides

Safety

• Symbol(GHS): GHS02,GHS05
• Signal word: Danger
• Hazard statements: H228-H261-H314
• Precautionary statements: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338
• Hazard Codes: C,F
• Risk Statements: 10-14/15-34-40-67-37
• Safety Statements: 26-36/37/39-45-16-43
• RIDADR: UN 2920 8/PG 2
• WGK Germany: 2
• F: 10-13
• HazardClass: 3.2
• PackingGroup: III