1,6-Hexamethylenediamine , AR,99.0% , 124-09-4
Synonym(s):
1,6-Diaminohexane;1,6-Hexanediamine;1,6-Hexanediamine, Hexamethylenediamine;HMDA
CAS NO.：124-09-4
Empirical Formula: C6H16N2
Molecular Weight: 116.2
MDL number: MFCD00008243
EINECS: 204-679-6
PRODUCT Properties
| Melting point: | 42-45 °C(lit.) |
| Boiling point: | 204-205 °C |
| Density | 0.89 g/mL at 25 °C(lit.) |
| vapor density | 4 (vs air) |
| vapor pressure | 0.25 hPa (20 °C) |
| refractive index | n |
| Flash point: | 201 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble(lit.) |
| pka | 11.857(at 0℃) |
| form | Solution |
| color | White, may discolor during storage |
| PH | 12.4 (100g/l, H2O, 25℃) |
| Odor | pyridine odor |
| explosive limit | 0.9-7.6%(V) |
| Water Solubility | 490 g/L (20 ºC) |
| Sensitive | Hygroscopic |
| Merck | 14,4695 |
| BRN | 1098307 |
| Exposure limits | ACGIH: TWA 0.5 ppm |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, organic materials. |
| LogP | 0.4 at 25℃ |
| CAS DataBase Reference | 124-09-4(CAS DataBase Reference) |
| NIST Chemistry Reference | 1,6-Hexanediamine(124-09-4) |
| EPA Substance Registry System | Hexamethylenediamine (124-09-4) |
Description and Uses
HMDA is a hygroscopic, colorless solid (pel-letsorflakes). Weak, fishy odor. odor thresh-old = 0.004 mg/m';Molecular weight = 116.13; Boilingpoint = 199℃; FreezingMelting point = 39- 42℃; Flashpoint= 71℃;81℃(solution);Autoi gnitiontemperature = 310℃. Explosive limits:LEL=0.7%;UEL= 6.3%. Soluble in water.
Hexamethylenediamine is mainly used as a monomer to make nylon 6-6. Its derivative hexamethylene diisocyanate (HDI) is used in the production of polyurethane. It acts as a cross-linking agent in epoxy resins. Other applications include fiber, plastics, polyurethane coatings, lubricants, water treatment products and specialty chemicals (biocides, petroleum additives, and phenol purification).
Safety
| Symbol(GHS) |   GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H302+H312-H314-H335 |
| Precautionary statements | P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338 |
| Hazard Codes | C |
| Risk Statements | 34-37-21/22-20/21/22 |
| Safety Statements | 26-36/37/39-45-22-27 |
| RIDADR | UN 2735 8/PG 3 |
| WGK Germany | 3 |
| RTECS | MO1180000 |
| F | 10-34 |
| Autoignition Temperature | 305 °C |
| TSCA | Yes |
| HS Code | 2921 22 00 |
| HazardClass | 8 |
| PackingGroup | III |
| Hazardous Substances Data | 124-09-4(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 850 mg/kg LD50 dermal Rabbit 1110 mg/kg |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
