Iridium acetylacetonate , ≥97% , 15635-87-7

Synonym(s):
Ir(acac)₃

CAS NO.：15635-87-7

Empirical Formula: C15H21IrO6

Molecular Weight: 489.54

MDL number: MFCD00015353

EINECS: 239-711-8

PRODUCT Properties

• Melting point: 269-271 °C(lit.)
• Boiling point: 260°C/1mmHg
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• solubility: slightly soluble in H2O; soluble in toluene, chloroform,acetone, methanol
• form: Crystalline
• color: Orange-yellow
• Water Solubility: Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol.
• Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
• InChI: InChI=1S/3C5H8O2.Ir/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-
• InChIKey: HLYTZTFNIRBLNA-LNTINUHCSA-K
• SMILES: [Ir](O/C(/C)=C\C(=O)C)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C
• NIST Chemistry Reference: Iridium, tris(2,4-pentanedionato-o,o')-, (oc-6-11)-(15635-87-7)

Description and Uses

Iridium(III) acetylacetonate is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.

Safety

• Symbol(GHS): GHS07,GHS08
• Signal word: Warning
• Hazard statements: H302+H312+H332-H315-H319-H335-H351
• Precautionary statements: P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313
• target organs: Respiratory system
• PPE: dust mask type N95 (US), Eyeshields, Gloves
• Hazard Codes: Xn
• Risk Statements: 20/21/22-36/37/38-40
• Safety Statements: 45-37/39-36/37/39-26
• WGK Germany: 3
• TSCA: No
• HS Code: 28439000
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Acute Tox. 4 Dermal; Acute Tox. 4 Inhalation; Acute Tox. 4 Oral; Carc. 2; Eye Irrit. 2; Skin Irrit. 2; STOT SE 3