N-Methylaniline , Analysis of standard products, ≥99.0%(GC) , 100-61-8
Synonym(s):
Monomethylaniline;N-Methylaniline
CAS NO.：100-61-8
Empirical Formula: C7H9N
Molecular Weight: 107.15
MDL number: MFCD00008283
EINECS: 202-870-9
PRODUCT Properties
| Melting point: | -57 °C (lit.) |
| Boiling point: | 196 °C (lit.) |
| Density | 0.989 g/mL at 25 °C (lit.) |
| vapor pressure | 0.5 hPa (20 °C) |
| refractive index | n |
| Flash point: | 174 °F |
| storage temp. | Store below +30°C. |
| solubility | water: slightly soluble30g/L |
| form | Liquid |
| pka | 4.84(at 25℃) |
| color | Clear yellow to brown |
| Odor | Moderate aniline-type. |
| PH | 7.6 (1g/l, H2O, 20℃) |
| Water Solubility | 30 g/L |
| Sensitive | Air Sensitive |
| Merck | 14,6019 |
| BRN | 741982 |
| Henry's Law Constant | (x 10-5 atmm3/mol):
1.19 at 25 °C (approximate - calculated from water solubility and vapor pressure) |
| Dielectric constant | 6.0（22℃） |
| Exposure limits | ACGIH:TLV-TWA 0.5 ppm (2.2 mg/m3) OSHA:PEL-TWA 2 ppm (9 mg/m3) NIOSH:REL-TWA 0.5 ppm |
| Stability: | Incompatible with strong oxidizing agents. Discolours upon exposure to air. |
| InChI | 1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3 |
| InChIKey | AFBPFSWMIHJQDM-UHFFFAOYSA-N |
| SMILES | CNc1ccccc1 |
| LogP | 1.66 at 20℃ |
| CAS DataBase Reference | 100-61-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Aniline, N-methyl-(100-61-8) |
| EPA Substance Registry System | N-Methylaniline (100-61-8) |
Description and Uses
N-Methylaniline is a yellow to light brown oily liquid with a weak, ammonia-like odor. Turns reddishbrown if left standing. The odor threshold is 1.7 ppm. Molecular weight= 107.17; Specific gravity (H2O:1)= 0.99;Boiling point=195.6℃; Freezing/Melting point=57.2℃; Vapor pressure= 0.3 mmHg at 20℃; Flash point=79.4℃. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 2, Reactivity 0. Practically insoluble in water.
N-Methylaniline is used as a solvent and in organic synthesis. It is used in the production of cationic brilliant red FG, cationic pink B, reactive yellow brown KGR, etc. in the dye industry. N-methylaniline is an intermediate in the synthesis of the insecticide buprofezin and the herbicide mefenacet.
Safety
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H301+H311+H331-H315-H319-H371-H372-H370-H335-H410-H227 |
| Precautionary statements | P501-P273-P270-P260-P210-P271-P264-P280-P370+P378-P391-P337+P313-P305+P351+P338-P308+P311-P361+P364-P332+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P403+P235-P405 |
| target organs | Liver,spleen,Bone marrow |
| PPE | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
| Hazard Codes | T,N |
| Risk Statements | 23/24/25-33-50/53 |
| Safety Statements | 28-36/37-45-60-61-28A |
| RIDADR | UN 2294 |
| OEB | B |
| OEL | TWA: 0.5 ppm (2 mg/m3) [skin] |
| WGK Germany | 3 |
| RTECS | BY4550000 |
| F | 8 |
| Autoignition Temperature | 500 °C |
| TSCA | TSCA listed |
| HazardClass | 6.1 |
| PackingGroup | III |
| HS Code | 29214200 |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 Eye Irrit. 2 STOT RE 2 Oral |
| Hazardous Substances Data | 100-61-8(Hazardous Substances Data) |
| Toxicity | LD in rabbits (g/kg): 0.28 orally; in rabbits, cats (mg/kg): 24, 24 i.v. (Treon) |
| IDLA | 100 ppm |
| REACH Registrations | Active |
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid) |
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) |
