A5590912
4-Methoxybenzyl 2,2,2-Trichloroacetimidate , >96.0%(GC) , 89238-99-3
CAS NO.：89238-99-3
Empirical Formula: C10H10Cl3NO2
Molecular Weight: 282.55
MDL number: MFCD00134547
| Pack Size | Price | Stock | Quantity |
| 1G | RMB141.60 | In Stock |
|
| 5G | RMB472.80 | In Stock |
|
| 25g | RMB1599.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 137 °C / 0.7mmHg |
| Density | 1.361 g/mL at 25 °C |
| refractive index | n20/D 1.5488 |
| Flash point: | 110 °C |
| storage temp. | 2-8°C |
| pka | 1.96±0.70(Predicted) |
| form | clear liquid |
| color | Colorless to Light yellow to Light orange |
| InChI | InChI=1S/C10H10Cl3NO2/c1-15-8-4-2-7(3-5-8)6-16-9(14)10(11,12)13/h2-5,14H,6H2,1H3 |
| InChIKey | TYHGKLBJBHACOI-UHFFFAOYSA-N |
| SMILES | C(=N)(OCC1=CC=C(OC)C=C1)C(Cl)(Cl)Cl |
Description and Uses
4-Methoxybenzyl-2,2,2-trichloroacetimidate can be used as a reagent for the protection of alcohols as the p-methoxybenzyl ether. 1o, 2o, and 3o alcohols can be easily protected using this reagent with equal efficiency in the presence of a variety of different protective groups. This reagent is commonly used under acidic conditions therefore it offers an alternative method to the Williamson ether synthesis, which is typically used basic conditions to protect base-sensitive alcohols.
Safety
| Symbol(GHS) |   GHS07,GHS09 |
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315-H319-H335-H411 |
| Precautionary statements | P273-P280-P301+P312+P330-P302+P352+P312-P304+P340+P312-P305+P351+P338 |
| Hazard Codes | Xn,N |
| Risk Statements | 20/21/22-36/37/38-51/53 |
| Safety Statements | 26-61-36/37 |
| RIDADR | UN 3082 9/PG 3 |
| WGK Germany | 3 |
| HS Code | 29252900 |
