(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferro , 97% , 55700-44-2

CAS NO.：55700-44-2

Empirical Formula: C26H28FeNP10*

Molecular Weight: 441.33

MDL number: MFCD00075286

EINECS: 633-502-9

PRODUCT Properties

• Melting point: 141-143 °C(lit.)
• alpha: -355 º (C=0.6 IN ETOH)
• storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• form: solid
• color: Light yellow to Yellow to Orange
• optical activity: [α]20/D 355°, c = 0.6 in ethanol
• Water Solubility: Insoluble in water.
• Sensitive: Air Sensitive
• InChI: 1S/C21H23NP.C5H5.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-2-4-5-3-1;/h4-17H,1-3H3;1-5H;/t17-;;/m1../s1
• InChIKey: RCAFPSZHKFOLEE-ZEECNFPPSA-N
• SMILES: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)C

Description and Uses

Ligand used in the enantioselective vinylation of aldehydes.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302-H312-H315-H319-H332-H335
• Precautionary statements: P261-P280-P305+P351+P338-P280a-P304+P340-P405-P501a
• target organs: Respiratory system
• PPE: dust mask type N95 (US), Eyeshields, Gloves
• Hazard Codes: Xn
• Risk Statements: 20/21/22-36/37/38
• Safety Statements: 26-36-36/37/38
• RIDADR: 3288
• WGK Germany: 3
• HazardClass: 6.1
• PackingGroup: III
• HS Code: 29319090
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Acute Tox. 4 Dermal; Acute Tox. 4 Inhalation; Acute Tox. 4 Oral; Eye Irrit. 2; Skin Irrit. 2; STOT SE 3