(R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate , 98% , 791616-63-2

Synonym(s):
(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide;(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide;(R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-bi-2-naphthol cyclic monophosphate;(R)-TRIP;(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-bi-2-naphthol cyclic monophosphate

CAS NO.：791616-63-2

Empirical Formula: C50H57O4P

Molecular Weight: 752.98

MDL number: MFCD10567009

PRODUCT Properties

• Boiling point: 814.2±75.0 °C(Predicted)
• Density: 1.17±0.1 g/cm3(Predicted)
• storage temp.: Inert atmosphere,Room Temperature
• pka: 1.12±0.20(Predicted)
• form: Powder
• color: white to light-yellow
• InChIKey: AGQAQYPGJDBIQR-UHFFFAOYSA-N
• SMILES: O=P1(OC2C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)C=2O1)O

Description and Uses

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Safety

• Symbol(GHS): GHS07
• Signal word: Danger
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280-P305+P351+P338-P304+P340-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• TSCA: No
• HS Code: 29199000