(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl , 98% , 100165-88-6

Synonym(s):
(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl;(S)-(−)-2,2′-p-tolyl-phosphino)-1,1′-binaphthyl;(S)-Tol-BINAP

CAS NO.：100165-88-6

Empirical Formula: C48 H40 P2

Molecular Weight: 678.78

MDL number: MFCD00269856

EINECS: 1312995-182-4

PRODUCT Properties

• Melting point: 252-256 °C
• alpha: -160° (c 0.5, C6H6)
• Boiling point: 754.4±60.0 °C(Predicted)
• storage temp.: Inert atmosphere,Room Temperature
• form: Powder
• color: White
• optical activity: [α]20/D -156°, c = 0.5 in benzene
• Water Solubility: Insoluble in water.
• InChIKey: IOPQYDKQISFMJI-UHFFFAOYSA-N
• SMILES: P(C1C=CC(C)=CC=1)(C1C=CC(C)=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1
• CAS DataBase Reference: 100165-88-6(CAS DataBase Reference)

Description and Uses

(S)-T-BINAP reacts with silver nitrate to form (S)-Tol-BINAP·AgNO₃, which can catalyze the enantioselective allylation reaction of aldehydes to form enantiopure secondary alcohols. It may be used as a chiral ligand in the palladium catalyzed asymmetric double carbohydroamination of iodoarenes to form α-aminoamides. It can also catalyze the asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate to form chiral N-allyl ortho-tert-butylanilides.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Risk Statements: 36/37/38
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• TSCA: No
• HS Code: 29333990