Titanium ethoxide , 33-35%TiO2 , 3087-36-3

Synonym(s):
Tetraethyl orthotitanate;Tetraethyl titanate

Update time: 2022-07-08

Melting point:	54°C
Boiling point:	150-152 °C10 mm Hg(lit.)
Density	1.088 g/mL at 25 °C(lit.)
vapor pressure	57.26hPa at 19.6℃
refractive index	n20/D 1.505(lit.)
Flash point:	84 °F
storage temp.	2-8°C
solubility	Soluble in organic solvents.
form	Liquid
Specific Gravity	1.107 (20℃)
color	Pale yellow
Water Solubility	reacts
Sensitive	Moisture Sensitive
BRN	3678992
Exposure limits	ACGIH: TWA 200 ppm; STEL 400 ppm OSHA: TWA 400 ppm(980 mg/m3) NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability:	Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKey	JMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP	-0.3 at 25℃
CAS DataBase Reference	3087-36-3(CAS DataBase Reference)
NIST Chemistry Reference	Ti(OEt)4(3087-36-3)
EPA Substance Registry System	Ethanol, titanium(4+) salt (3087-36-3)

Titanium(IV) ethoxide can be used:

As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti⁴⁺ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Symbol(GHS)	GHS02,GHS07
Signal word	Warning
Hazard statements	H226-H319
Precautionary statements	P210-P305+P351+P338
Hazard Codes	Xi
Risk Statements	10-36/37/38-67
Safety Statements	26-37/39-16
RIDADR	UN 1993 3/PG 3
WGK Germany	3
F	3-10-21
TSCA	Yes
HazardClass	4.1
PackingGroup	III
HS Code	29051900
Limited Quantities	5.0 L (1.3 gallons) (liquid)
Excepted Quantities	Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)