4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) , ≥93.0% , 75927-49-0

Synonym(s):
2-Ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaoborolane;4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane

Update time: 2022-07-08

Boiling point:	52-54°C 24mm
Density	0.908 g/mL at 25 °C (lit.)
refractive index	n20/D 1.4300(lit.)
Flash point:	94 °F
storage temp.	-20°C
solubility	Chloroform (Sparingly), Methanol (Slightly)
form	Powder or Low Melting Solid
color	White to yellow
Sensitive	Air Sensitive
Stability:	Light Sensitive, Volatile
InChI	InChI=1S/C8H15BO2/c1-6-9-10-7(2,3)8(4,5)11-9/h6H,1H2,2-5H3
InChIKey	DPGSPRJLAZGUBQ-UHFFFAOYSA-N
SMILES	O1C(C)(C)C(C)(C)OB1C=C
CAS DataBase Reference	75927-49-0(CAS DataBase Reference)

Reagent used for

Suzuki-Miyaura coupling reactions
Mizoroki-Heck reactions (cascade reaction)
Intramolecular Nozaki-Hiyama-Kishi reactions
Stereoselective Cu-catalyzed γ-selective and stereospecific coupling
Control of stereoselectivity and mechanistic portrait on intramolecular (4+1)-cycloaddition of dialkoxycarbenes
Regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes followed by Pd-catalyzed consecutive cross-coupling reactions
Asymmetric Birch reductive alkylation

Reagent used in Preparation of

Molecular tubes for lipid sensing
Enzymatic inhibitors, antibiotics, receptor analogs, and other biologically significant compounds (including total syntheses)

Symbol(GHS)	GHS02,GHS07,GHS09
Signal word	Warning
Hazard statements	H226-H317-H411
Precautionary statements	P210-P233-P240-P273-P280-P303+P361+P353
Hazard Codes	Xi
Risk Statements	10-43
Safety Statements	16-36/37
RIDADR	UN 3272 3/PG 3
WGK Germany	3
TSCA	No
HazardClass	3
PackingGroup	III
HS Code	29319090
Limited Quantities	5.0 L (1.3 gallons) (liquid)
Excepted Quantities	Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)