Home Categories Organic Chemistry 5,10,15,20-<WBR>Tetraphenyl-<WBR>21<I>H</I>,23<I>H</I>-porphine nickel(II)
A8026012

5,10,15,20-<WBR>Tetraphenyl-<WBR>21<I>H</I>,23<I>H</I>-porphine nickel(II) , 95% , 14172-92-0

Synonym(s):
Nickel TPP

CAS NO.:14172-92-0

Empirical Formula: C44H28N4Ni

Molecular Weight: 671.41

MDL number: MFCD00010727

Pack Size Price Stock Quantity
250MG RMB187.20 In Stock
500MG RMB399.20 In Stock
1g RMB713.60 In Stock
5g RMB2645.60 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: >300 °C
storage temp.  2-8°C, protect from light, stored under nitrogen
form  crystal
color  purple
Water Solubility  Insoluble in H2O; soluble in CHCl3; slightly soluble in ether, benzene, hexane, and methanol.
λmax 525 nm (2nd)
InChIKey CXIRWLOIAQYBLZ-DAJBKUBHSA-N
SMILES N12[Ni]N3C4C=CC3=C(C3C=CC(N=3)=C(C3=CC=CC=C3)C1=CC=C2C(C1=CC=CC=C1)=C1C=CC(C=4C2=CC=CC=C2)=N1)C1=CC=CC=C1 |c:7,14,41,t:36|

Description and Uses

Nickel(II) Tetraphenylporphyrinate is an electron transfer agent and catalyst for aryl halogen exchange reactions. It could be used in cyclizations of saturated ο-iodo ketones and hydrogenation of alkenes.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/21/22
Safety Statements  37/39-26-36
WGK Germany  3
HS Code  29310099

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