Vanadium(III) chloride , 97% , 7718-98-1

Synonym(s):
Vanadium trichloride;Vanadium(III) chloride

CAS NO.：7718-98-1

Empirical Formula: Cl3V

Molecular Weight: 157.29

MDL number: MFCD00011454

EINECS: 231-744-6

PRODUCT Properties

• Melting point: 250 °C
• Density: 3 g/mL at 25 °C(lit.)
• bulk density: 1000kg/m3
• storage temp.: no restrictions.
• solubility: Soluble in tetrahydrofuran, alcohol, ether and hydrocarbons.
• form: Powder
• Specific Gravity: 3.
• color: Dark blue to violet to black
• Water Solubility: decomposes in H2O; soluble alcohol, ether [HAW93]
• Sensitive: Moisture Sensitive
• Crystal Structure: BiI3 type
• crystal system: Three sides
• Space group: R3
• Lattice constant:
  • a/nm: 0.601
  • b/nm: 0.601
  • c/nm: 1.734
  • α/o: 90
  • β/o: 90
  • γ/o: 120
  • V/nm3: 0.5428
• Exposure limits: NIOSH: Ceiling 0.05 mg/m3
• CAS DataBase Reference: 7718-98-1(CAS DataBase Reference)
• EPA Substance Registry System: Vanadium chloride (VCl3) (7718-98-1)

Description and Uses

Preparation of vanadium dichloride and organovanadium compounds.

Safety

• Symbol(GHS): GHS05,GHS07
• Signal word: Danger
• Hazard statements: H302-H314
• Precautionary statements: P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
• Hazard Codes: C
• Risk Statements: 22-34
• Safety Statements: 26-27-28-36/39-45
• RIDADR: UN 2475 8/PG 3
• WGK Germany: 3
• RTECS: YW2800000
• F: 3-10
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• HS Code: 28273990
• Toxicity: LD50 orally in Rabbit: 350 mg/kg
• Limited Quantities: 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
• Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)