Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium , 98% , 677736-23-1

Synonym(s):
Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

CAS NO.：677736-23-1

Empirical Formula: C35H25.2CO.ClRu

Molecular Weight: 638.125

MDL number: MFCD09265041

PRODUCT Properties

• Melting point: 152-167 °C
• storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
• form: solid
• Appearance: Light yellow to yellow Solid
• InChIKey: NGSBLRJKXUHTOC-UHFFFAOYSA-M
• SMILES: [C]1([C](C2C=CC=CC=2)[C]([C](C2C=CC=CC=2)[C]1C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[O+]#[C-].[O+]#[C-].[Ru]Cl |^1:0,1,8,9,16|

Description and Uses

Reactant for:

• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
• Ligand exchange
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:

• (S)-Selective dynamic kinetic resolution of secondary alcohols
• Stereoselective synthesis of neonicorinoide pesticide derivatives
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P264-P271-P280-P302+P352-P305+P351+P338
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3