Home Categories Organic Chemistry Chlorodi(2-furyl)phosphine
F607923

Chlorodi(2-furyl)phosphine , 98+ , 181257-35-2

Synonym(s):
Di-2-furanylphosphinous chloride

CAS NO.:181257-35-2

Empirical Formula: C8H6ClO2P

Molecular Weight: 200.56

MDL number: MFCD01630851

Pack Size Price Stock Quantity
1g RMB1079.20 In Stock
5g RMB5301.60 In Stock
others     Enquire
Update time: 2022-07-08

PRODUCT Properties

Boiling point: 102-104°C/14mm
Density  1.287 g/mL at 25 °C
Flash point: 102-104°C/14mm
refractive index  1.5930
form  liquid
Water Solubility  Reacts with water.
Sensitive  Moisture Sensitive
InChI 1S/C8H6ClO2P/c9-12(7-3-1-5-10-7)8-4-2-6-11-8/h1-6H
InChIKey IYEUYNXDXNWPJI-UHFFFAOYSA-N
SMILES ClP(c1ccco1)c2ccco2

Description and Uses

Reactant for synthesis of:

  • Centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands
  • Ferrocene-based chiral diphosphine
  • Phosphine containing amino acids

Reactant for:
  • α-Arylation of aldehydes
  • Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites
  • Hydrophosphination of functionalized alkenes

Safety

Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H261-H314
Precautionary statements  P231+P232-P280-P305+P351+P338-P310-P422
Hazard Codes  C
Risk Statements  14-34
Safety Statements  26-36/37/39-45
RIDADR  UN3265
WGK Germany  3
HazardClass  8
PackingGroup  II
Storage Class 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications Skin Corr. 1B
Water-react 2

RELATED PRODUCTS