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S9323248

Maneb , PESTANAL?,analyticalstandard , 12427-38-2

Synonym(s):
Manganese ethylenebis(dithiocarbamate)

CAS NO.:12427-38-2

Empirical Formula: C4H6MnN2S4

Molecular Weight: 265.3

MDL number: MFCD00046858

EINECS: 235-654-8

Update time: 2022-07-08

PRODUCT Properties

Melting point: 131°C
Density  1.92 g/cm3(Temp: 25 °C)
vapor pressure  Negligible at 20 °C
storage temp.  0-6°C
Water Solubility  Insoluble in water
form  solid
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Merck  13,5743
BRN  3747585
Major Application agriculture
environmental
InChI 1S/C4H8N2S4.Mn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2
InChIKey YKSNLCVSTHTHJA-UHFFFAOYSA-L
SMILES S=C1NCCNC(=S)S[Mn]S1
CAS DataBase Reference 12427-38-2(CAS DataBase Reference)
IARC 3 (Vol. 12, Sup 7) 1987
EPA Substance Registry System Maneb (12427-38-2)

Description and Uses

Maneb is a pesticide with fungicide properties and belongs to the carbamate (bis-dithiocarbamate) group. Sensitization occurs mainly in farmers and agricultural workers.

Maneb is a complex of manganese with the ethylene bis(dithiocarbamate) anionic ligand. Maneb is a foliate fungicide used to protect crops in agriculture. Maneb is also useful in creating a toxin-based animal (usually primates) model of Parkinson's disease.

Safety

Symbol(GHS) 
GHS07,GHS08,GHS09
Signal word  Warning
Hazard statements  H317-H319-H332-H361d-H410
Precautionary statements  P273-P280-P302+P352-P304+P340+P312-P305+P351+P338-P308+P313
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xi,N,Xn
Risk Statements  20/21/22-43-37-50/53-36-20-63
Safety Statements  22-36/37/39-46-24/25-8-61-60-36/37
RIDADR  2210
WGK Germany  1
RTECS  OP0700000
TSCA  No
HazardClass  4.2
PackingGroup  III
Storage Class 4.2 - Pyrophoric and self-heating hazardous materials
Hazard Classifications Acute Tox. 4 Inhalation
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Repr. 2
Skin Sens. 1
Hazardous Substances Data 12427-38-2(Hazardous Substances Data)
Toxicity LD50 oral in rat: 3gm/kg

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