Home Categories Chemical pesticides Chloromethyl Ethyl Ether
T8167730

Chloromethyl Ethyl Ether , >96.0%(GC) , 3188-13-4

CAS NO.:3188-13-4

Empirical Formula: C3H7ClO

Molecular Weight: 94.54

MDL number: MFCD00000887

EINECS: 221-687-5

Update time: 2022-07-08

PRODUCT Properties

Melting point: -104°C
Boiling point: 82 °C(lit.)
Density  1.019 g/mL at 25 °C(lit.)
refractive index  n20/D 1.404(lit.)
Flash point: 67 °F
storage temp.  0-6°C
solubility  Chloroform (Soluble), Ethyl Acetate (Slightly)
form  Liquid
color  Clear colorless to pale yellow
Specific Gravity 1.019
InChI InChI=1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
InChIKey FCYRSDMGOLYDHL-UHFFFAOYSA-N
SMILES CCOCCl
CAS DataBase Reference 3188-13-4(CAS DataBase Reference)
NIST Chemistry Reference Ethane, (chloromethoxy)-(3188-13-4)
EPA Substance Registry System Ethane, (chloromethoxy)- (3188-13-4)

Description and Uses

Chloromethyl ethyl ether can be used to prepare:

  • 6-Benzyl-1-(ethoxymethyl)-5-iodopyrimidine-2,4(1H,3H)-dione, a key intermediate in the preparation of MKC-442 analog.
  • Acylation catalyst for alcohols named 1,3-bis-[(R)-1-(2-naphthyl)ethyl]imidazoliumchloride by reacting with glyoxal-bis-[(R)-1-(2-naphthyl)ethyl]imine.

Safety

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)Health Hazard (GHS08)
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H301+H311+H331-H314-H341-H336-H225
Precautionary statements  P501-P270-P202-P240-P261-P210-P233-P201-P243-P241-P242-P271-P264-P280-P370+P378-P308+P313-P361+P364-P303+P361+P353-P301+P330+P331-P301+P310+P330-P304+P340+P310-P305+P351+P338+P310-P403+P233-P403+P235-P405
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  F,Xn
Risk Statements  11-20/21/22-36-40
Safety Statements  16-36/37-9-45-29
RIDADR  UN 2354
WGK Germany  3
TSCA  TSCA listed
HazardClass  3
PackingGroup  II
HS Code  29091990
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Flam. Liq. 2
Hazardous Substances Data 3188-13-4(Hazardous Substances Data)
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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