Di-tert-butylchlorophosphine , >95.0%(GC) , 13716-10-4

CAS NO.：13716-10-4

Empirical Formula: C8H18ClP

Molecular Weight: 180.66

MDL number: MFCD00008815

PRODUCT Properties

• Melting point: 2-3°C
• Boiling point: 48 °C/3 mmHg (lit.)
• Density: 0.951 g/mL at 25 °C (lit.)
• refractive index: n20/D 1.482(lit.)
• Flash point: 142 °F
• solubility: Miscible with terahydrofuran.
• form: Liquid
• Specific Gravity: 0.951
• color: Clear colorless
• Sensitive: Air & Moisture Sensitive
• InChI: InChI=1S/C8H18ClP/c1-7(2,3)10(9)8(4,5)6/h1-6H3
• InChIKey: MCRSZLVSRGTMIH-UHFFFAOYSA-N
• SMILES: P(C(C)(C)C)(C(C)(C)C)Cl
• CAS DataBase Reference: 13716-10-4(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)

Description and Uses

Bulky ligand used with Pd(OAc)₂ in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
• Hazard Codes: C
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45-25
• RIDADR: UN 3265 8/PG 2
• WGK Germany: 3
• TSCA: No
• HazardClass: 8
• PackingGroup: II
• HS Code: 29310099