S6085749
Triphenyltinhydroxide , 76-87-9
Synonym(s):
Triphenyltin hydroxide;Fentin hydroxide;Hydroxytriphenylstannane;K19;Keratin type I cytoskeletal 19
CAS NO.：76-87-9
Empirical Formula: C18H16OSn
Molecular Weight: 367.03
MDL number: MFCD00013928
EINECS: 200-990-6
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 124-126 °C (lit.) |
| Boiling point: | 428.5±28.0 °C(Predicted) |
| Density | 1.54 |
| storage temp. | -20°C |
| solubility | Slightly soluble in alcohol, toluene |
| form | Powder |
| pka | 3.98±0.70(Predicted) |
| color | Off-white |
| biological source | rabbit |
| Water Solubility | <0.1 g/100 mL at 21 ºC |
| Merck | 14,9745 |
| BRN | 4139186 |
| Exposure limits | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin) NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| Major Application | agriculture cleaning products cosmetics environmental food and beverages personal care |
| InChI | 1S/3C6H5.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1-5H;1H2;/q;;;;+1/p-1 |
| InChIKey | BFWMWWXRWVJXSE-UHFFFAOYSA-M |
| SMILES | O[Sn](c1ccccc1)(c2ccccc2)c3ccccc3 |
| CAS DataBase Reference | 76-87-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Stannane, hydroxytriphenyl-(76-87-9) |
| EPA Substance Registry System | Triphenyltin hydroxide (76-87-9) |
Description and Uses
Reactant involved in transmetalation reactions with Ir clusters. Reactant involved in synthesis of (E)-(Nitrophenyl)propenoic acid organotin(IV) carboxylates with antitumor activity, triorganotin chrysanthemumates for larvicidal studies, polynuclear organotin(IV) carboxylates containing ferrocenyl moieties for antitumor investigation, organotin(IV) aminophenylacrylate complexes, 4-Biphenylcarboxylic acid derivatives for in vitro cytotoxicity studies.
Safety
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H300+H330-H311-H315-H318-H335-H351-H361d-H371-H372-H410 |
| Precautionary statements | P202-P273-P280-P302+P352+P312-P304+P340+P310-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |
| Hazard Codes | T+,N |
| Risk Statements | 24/25-26-37/38-40-41-48/23-50/53-63-36/37/38 |
| Safety Statements | 26-28-36/37/39-45-60-61 |
| RIDADR | UN 3146 6.1/PG 2 |
| WGK Germany | 3 |
| RTECS | WH8575000 |
| TSCA | TSCA listed |
| HazardClass | 6.1 |
| PackingGroup | III |
| HS Code | 29319090 |
| Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials |
| Hazard Classifications | Acute Tox. 2 Inhalation Acute Tox. 2 Oral Acute Tox. 3 Dermal Aquatic Acute 1 Aquatic Chronic 1 Carc. 2 Eye Dam. 1 Repr. 2 Skin Irrit. 2 STOT RE 1 STOT SE 2 STOT SE 3 |
| Hazardous Substances Data | 76-87-9(Hazardous Substances Data) |
| Toxicity | LD50 oral in rat: 46mg/kg |
