Home Categories Chemical Reagents (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine 98%
A7124012

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine 98% , 98% , 144222-34-4

CAS NO.:144222-34-4

Empirical Formula: C21H22N2O2S

Molecular Weight: 366.48

MDL number: MFCD02093428

Pack Size Price Stock Quantity
1G RMB88.00 In Stock
5G RMB358.40 In Stock
25G RMB1518.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 128-131 °C(lit.)
alpha  -61.5 º (c=1, CH2Cl2)
Boiling point: 537.3±60.0 °C(Predicted)
Density  1.1440 (rough estimate)
refractive index  -30 ° (C=0.4, CHCl3)
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
solubility  Chloroform, Methanol
pka 10.76±0.50(Predicted)
form  Crystals or Crystalline Powder
color  White to slightly yellow
optical activity [α]20/D 35°, c = 1 in chloroform
Water Solubility  insoluble
InChI InChI=1S/C21H22N2O2S/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17/h2-15,20-21,23H,22H2,1H3/t20-,21-/m1/s1
InChIKey UOPFIWYXBIHPIP-NHCUHLMSSA-N
SMILES C1(S(N[C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)(=O)=O)=CC=C(C)C=C1
CAS DataBase Reference 144222-34-4(CAS DataBase Reference)

Description and Uses

Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29215900

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