Home Categories Organic Chemistry 2-Bromo-1,3,5-tri-tert-butylbenzene
BD0968632

2-Bromo-1,3,5-tri-tert-butylbenzene , 97% , 3975-77-7

CAS NO.:3975-77-7

Empirical Formula: C18H29Br

Molecular Weight: 325.33

MDL number: MFCD00191861

Pack Size Price Stock Quantity
100mg RMB32.00 In Stock
250mg RMB39.20 In Stock
1g RMB83.20 In Stock
5g RMB315.20 In Stock
10g RMB592.00 In Stock
25g RMB1313.60 In Stock
100g RMB4879.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 168-173 °C (lit.)
Boiling point: 299.7±9.0 °C(Predicted)
Density  1.064±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
Appearance White to off-white Solid
BRN  1913257
InChI InChI=1S/C18H29Br/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,1-9H3
InChIKey JOKZWHPYNRDCOA-UHFFFAOYSA-N
SMILES C1(C(C)(C)C)=CC(C(C)(C)C)=CC(C(C)(C)C)=C1Br

Description and Uses

1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3

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